To learn more, see our tips on writing great answers. BeO and Be (OH)2 are amphoteric and react with acids and strong bases such as NaOH. Group II metal oxide basicity and hydroxide solubility in water increase as you go down the column. why is the melting point of calcium sulfate high, Doubt about the trends of entropy for hydration of ions, IAL Physics and Chemistry revision songs, MK II, Ial chemistry unit 3 may 2018 send ur Answers here. Therefore, the shorter the bond, the higher the lattice enthalpy. If acidified Barium Chloride is added to a solution that contains sulphate ions a white precipitate of Barium Sulphate forms. What is the best way to remove 100% of a software that is not yet installed? Although it describes the trends, there isn't any attempt to explain them on this page - for … Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. I know that, solubility of alkaline earth metal hydroxides increases down the group and solubility of alkaline earth metal sulfates decreases down the group. Hydration enthalpy drops because the cations becomes bigger and So, the harder ions are, the more soluble with sulfate and less with hydroxide. The trends of solubility for hydroxides and sulfates are as follows: Contributors and Attributions. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. Hydration enthalpy is the energy released when one mole of gaseous ions is completely hydrated by water molecules under standard conditions. This answer could be improved by adding more information from the hyperlink. BaSO4 is the least soluble. I wish to understand the reason for these trends. $F\propto 1/r^{2}$. Therefore, the smaller the ion, the higher the hydration enthalpy. What is this part which is mounted on the wing of Embraer ERJ-145? PAG 4.1 Identifying unknowns help please? 9000 ft.) is 15,000 feet high? (Start typing, we will pick a forum for you), Taking a break or withdrawing from your course, Maths, science and technology academic help, Trend in Solubilities of Group 2 Sulfates. For Group 2, magnesium sulphate is soluble while strontium and barium sulphates are insoluble. rev 2020.11.24.38066, The best answers are voted up and rise to the top, Chemistry Stack Exchange works best with JavaScript enabled, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site, Learn more about Stack Overflow the company, Learn more about hiring developers or posting ads with us. I hope this helps and feel free to send me an e-mail if you have any doubts! This is due to increases in lattice energy of sulphate down the group which predominates over hydration energy. Why does the solubility of Group II hydroxides increase and the solubility of sulphates decrease down the group? site design / logo © 2020 Stack Exchange Inc; user contributions licensed under cc by-sa. John W. Lv 7. Sulfates Group 2 sulfates become less soluble down the group. Why should I expect that black moves Rxd2 after I move Bxe3 in this puzzle? MathJax reference. How to do calculations involving solubility? What are some methods to align switches in a multi-gang box? A few weeks ago I would have given the hard soft acid base theory (HSAB) explanation. Since the hydration enthalpy decreases faster than the lattice enthalpy in the case of Group 2 sulphates, the solubility of Group 2 sulphates decreases while progressing down the group. Calcium sulphate is particularly interesting because although it is only sparingly soluble its solubility is much higher than is expected from the solubility product. Thanks for contributing an answer to Chemistry Stack Exchange! Can someone explain the solubility of Group 2 compounds in a better way? The relationship between enthalpy of solution and solubility. Why do people call an n-sided die a "d-n"? We have a brilliant team of more than 60 Support Team members looking after discussions on The Student Room, helping to make it a fun, safe and useful place to hang out. Again, the hydration enthalpy decreases the same way as it does in the case of Group 2 cations bonded to OH⁻ ions. Look at this: http://www.chemguide.co.uk/inorganic/group2/solubility.html. ), Applying to uni? As you go down the group, the energy needed to break up the lattice falls as the positive ions get bigger. Why does the solubility of some salts decrease with temperature? What is the decisive point for classifying a certain speech as unacceptable? Meaning of the Term "Heavy Metals" in CofA? This is why the solubility of Group 2 hydroxides increases while progressing down the group. Making statements based on opinion; back them up with references or personal experience. By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy. Let's deal with $\ce{OH-}$ first. Since the hydration enthalpy decreases faster than the lattice enthalpy in the case of Group 2 sulphates, the solubility of Group 2 sulphates decreases while progressing down the group. Looking for a function that approximates a parabola. If we look at Coulomb's law, we find that the attractive force between two bodies with different charges is inversely proportional to the square of the distance apart between their centres of mass, i.e. Please critique. lattice hydration Mg Ca Sr Ba Ra energy Water molecules are more strongly attracted to smaller ions with a larger charge. Unit 2: CHEMICAL BONDING, APPLICATION OF CHEMICAL REACTIONS and ORGANIC CHEMISTRY. I have heard this "trend" explained in this way: Hydroxide is hard and sulfate is soft. SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER. Is this a homework question or a curiosity question? 9 years ago. Importance of “gerade” to express “just about to”. Are broiler chickens injected with hormones in their left legs? Reactivity of alkaline earth metals towards water, Apparent contradiction in the name of group 2 elements. 5 1. The Student Room, Get Revising and Marked by Teachers are trading names of The Student Room Group Ltd. Register Number: 04666380 (England and Wales), VAT No. 806 8067 22 Registered Office: International House, Queens Road, Brighton, BN1 3XE. It only takes a minute to sign up. Lattice enthalpy is the energy released when one mole of a compound is formed from its constituent gaseous ions under standard conditions. Group II sulphates become less soluble down the group. If the former, the "trend" isn't that trendy and the teacher should read the links above. Since the hydration enthalpy decreases faster than the lattice enthalpy in the case of Group 2 sulphates, the solubility of Group 2 sulphates decreases while progressing down the group. About a week ago I was playing around with some DH, lattice energy, and Ksp data and I found that barium seems to go against the "trend". Okay, for this scenario, the two concepts that play a key role are the lattice enthalpy and the hydration enthalpy. If the latter, do you know that barium salts tend to go against the "trend"? Here we shall look at the solubilities of the hydroxides and sulfates of Group 2 metals. Due to this, the distance between the centres of mass of the cation and the anion increases and by definition, the lattice enthalpy decreases. SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium.